Water quality guidelines for public aquatic facilities - December 2019 Page 20 of 70
The concentration of stock chlorine solutions can degrade quickly with improper storage. As
with all chemicals, chlorine should be stored in accordance with the label instructions.
When chlorine is added to water it forms a mixture of hypochlorous acid (a strong
disinfectant) and hypochlorite ions (a weaker disinfectant). Together, hypochlorous acid and
hypochlorite ion make up what is known as ‘free chlorine’.
The pH of the water will affect how much of the stronger disinfectant (hypochlorous acid) is
formed. To ensure free chlorine remains effective, pH is recommended to be maintained
within the range listed in Table A2.1 in Appendix 2. If the pH drops too low, it may affect bather
comfort; if it becomes too high the free chlorine will lose most of its disinfection power.
Free chlorine can react with nitrogen-containing contaminants in the water, such as
ammonia, to form ‘combined chlorine’ or ‘chloramine’. Combined chlorine is unwanted
because it is not only a poor disinfectant, but it can also cause skin irritation, eye irritation,
corrosion and a strong and offensive ‘chlorine smell’.
When added together, free and combined chlorine is called ‘total chlorine’. When
evaluating total chlorine values, the combined chlorine value should not exceed the level
stated in Table A2.1 in Appendix 2.
Chlorine demand
Chlorine demand reflects the amount of free chlorine that is lost or used up through reactions
with microorganisms and other contaminants in the water; it is the difference between the
amount of chlorine added to the water and the amount of free available chlorine or combined
chlorine remaining at the end of a specified time period. Chlorine demand is often relative to
the number of bathers but is ultimately related to the total amount of contaminants in the
water (leaves, dirt, cosmetics, sunscreen etc.). The greater the chlorine demand, the greater
the amount of chlorine that will need to be added to the water to ensure the minimum
recommended free chlorine level is maintained at all times. Chlorine demand can be reduced
by encouraging bathers to shower before they enter the water and designing public aquatic
facilities such that environmental contamination is minimised.
Stabilised chlorine
In outdoor facilities sunlight breaks down chlorine, which can lead to significant loses of
free chlorine. Stabilised chlorine (chlorine with cyanuric acid added to it) can be used to
address this issue because cyanuric acid bonds loosely to the free chlorine to minimise
the impact of UV light. It can be purchased as granules/tablets or can be formed by adding
cyanuric acid to water containing free chlorine.
The decision to use stabilised chlorine in an outdoor aquatic facility and the level at which it
is added should be balanced against the need for immediate remediation in the event of a
diarrhoeal incident or Cryptosporidium contamination incident (refer to Appendix 6). Use of
stabilised chlorine can affect the effectiveness of hyperchlorination procedures. For
hyperchlorination to be undertaken, cyanuric acid concentration levels need to be dropped
below 15 mg/L. This may involve partially draining the pool and adding fresh water.
The maximum level of cyanuric acid that is recommended to be added to an outdoor pool is
detailed in Table A2.1 in Appendix 2. Cyanuric acid reduces the disinfection power of
hypochlorous acid, therefore the minimum free chlorine level should be maintained at the
level listed in Table A2.1 in Appendix 2. Cyanuric acid should not be used in indoor pools.